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Asymptotic and interpolation series for the Coulomb three-body systems with unit charges

Published 30 Jan 2019 in physics.atom-ph | (1901.10749v2)

Abstract: Accurate mass-interpolation and mass-asymptotic formulas are derived for one- and two-center three-body ions with unit charges. The derived formulas are applied to predict accurate numerical values of the total energies of the ground (bound) 1<sup>1S(L</sup>=0)−1<sup>{1}S(L</sup> = 0)-states in one-center atomic ions X<sup>+</sup>e<sup>−</sup>e<sup>−X<sup>{+}</sup> e<sup>{-}</sup> e<sup>{-} and analogous ground (bound) 1sσ−1 s \sigma-states in the two-center, quasi-adiabatic (or quasi-molecular) X<sup>+</sup>X<sup>+</sup>e<sup>−X<sup>{+}</sup> X<sup>{+}</sup> e<sup>{-} ions. We also discuss a few problems which currently remain unsolved for the Q<sup>−1Q<sup>{-1} expansions constructed for the ground (bound) states in few-electron atoms and ions.

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