Thermoelectric generator at optimal power with external and internal irreversibilities

Abstract: There are few exact results on optimal power conditions for a thermoelectric generator in the presence of both external and internal irreversibilities---modelled as non-ideal thermal contacts and Joule heating, respectively. Simplified cases, where only one kind of irreversibility is assumed, yield some well-known expressions for efficiency at maximum power (EMP), such as Curzon-Ahlborn efficiency for endoreversible model. In this work, we analyze situations under the simultaneous presence of internal and external irreversibilities. To simplify, we neglect heat leaks, and each kind of irreversibility is assumed only on the side of one of the thermal contacts. We also present the symmetric case---where each kind of irreversibility contributes with equal strengths towards the side of each thermal contact. We show the bounds satisfied by EMP in each of these regimes and compare its properties for thermal impedence matching and close to equilibrium, where we find step-wise changes in EMP.