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Freezing-induced ordering of block copolymer micelles

Published 28 Mar 2018 in cond-mat.soft | (1803.10636v1)

Abstract: We demonstrate here the ordering of block copolymer micelles by ice templating, below 0 {\deg}C. We used this for the preparation of silica monoliths that present an ice-templated macroporosity, combined with a 2D hexagonal mesostructure templated by the addition of P123. We propose a mechanism triggered by the progressive freezing-induced concentration.

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