Orthogonal product bases of four qubits

Abstract: An orthogonal product basis (OPB) of a finite-dimensional Hilbert space $H=H_1\otimes H_2\otimes\cdots\otimes H_n$ is an orthonormal basis of $H$ consisting of product vectors $x_1\otimes x_2\otimes\cdots\otimes x_n$. We show that the problem of classifying the OPBs of an $n$-qubit system can be reduced to a purely combinatorial problem. We solve this combinatorial problem in the case of four qubits and obtain 33 multiparameter families of OPBs. Each OPB of four qubits is equivalent, under local unitary operations and qubit permutations, to an OPB belonging to at least one of these families.