Age and Structure of a Model Vapor-Deposited Glass (1606.04499v2)

Abstract: Glass films prepared by a process of physical vapor deposition have been shown to have thermodynamic and kinetic stability comparable to those of ordinary glasses aged for thousands of years. A central question in the study of vapor-deposited glasses, particularly in light of new knowledge regarding anisotropy in these materials, is whether the ultra-stable glassy films formed by vapor deposition are ever equivalent to those obtained by liquid cooling. We present a computational study of vapor deposition for a two-dimensional glass forming liquid using a methodology which closely mimics experiment. We find that for the model considered here, structures that arise in vapor-deposited materials are statistically identical to those observed in ordinary glasses, provided the two are compared at the same inherent structure energy. We also find that newly deposited hot molecules produce cascades of hot particles that propagate far into the film, possibly influencing the relaxation of the material.