Electrochemical Cells with Intermediate Capacitor Elements

Abstract: Our goal is to electronically regulate electrochemical cells. For this, we introduced a third element, called the gate, which was placed between the cathode and the anode electrodes of the cell. Voltage applied to this element controlled the local potential of the electrolyte, thus impacting the flow of ions within the cell. The flow of ions was monitored by the electronic current in the external cell's circuit. We provide simulations and experimental data as proof to the validity of this concept. This is but the first step towards a demonstration of a two-dimensional, bi-carrier ion transistors.