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Thermodynamics of nonadditive systems

Published 14 May 2015 in cond-mat.stat-mech | (1505.03767v1)

Abstract: The usual formulation of thermodynamics is based on the additivity of macroscopic systems. However, there are numerous examples of macroscopic systems that are not additive, due to the long-range character of the interaction among the constituents. We present here an approach in which nonadditive systems can be described within a purely thermodynamics formalism. The basic concept is to consider a large ensemble of replicas of the system where the standard formulation of thermodynamics can be naturally applied and the properties of a single system can be consequently inferred. After presenting the approach, we show its implementation in systems where the interaction decays as 1/r<sup>α1/r<sup>\alpha in the interparticle distance rr, with α\alpha smaller than the embedding dimension dd, and in the Thirring model for gravitational systems.

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