Atomic Scale Investigation of Dye Sensitized Solar Cells_Interface Structure and Dynamics

Abstract: Dye-sensitized solar cells (DSC), built upon organic/inorganic hybrid materials, are promising third generation solar cells, which attract wide attentions due to their low-cost, flexibility and environment-friendly properties. We review recent progresses in DSC research, focusing on atomic-scale investigations of the interface electronic structures and dynamical processes, including dye adsorption structure onto TiO2, ultrafast electron injection, hot-electron injection, multiple-exciton generation and electron-hole recombination. We briefly summarize advanced experimental techniques and theoretical approaches investigating these interface electronic properties and dynamics, and then introduce progressive achievements in the photovoltaic device optimization based on insights obtained from atomic scale investigations. Finally, some challenges and opportunities for further improvement of dye solar cells are presented.