A Rubber-Modified Thermoplastic where the Morphology Produced by Phase-Separation Induced by Polymerization Disappears at High Conversions

Abstract: An unexpected experimental finding is reported where the primary morphology developed during polymerization-induced phase separation in a rubber-modified thermoplastic disappears at high conversions. This process was evidenced by light scattering (LS) and scanning electron microscopy (SEM) for a particular composition of solutions of polyisobutylene oligomers (PIB) in isobornylmethacrylate (IBoMA), during the free-radical polymerization of the monomer. The primary phase separation produced a dispersion of domains rich in PIB containing significant amounts of the monomer (IBoMA). Polymerization of the monomer in these domains occurred at high overall conversions producing the filling of dispersed domains with a PIBoMA-PIB blend. Under these conditions the final material had the appearance of a homogeneous blend. The process might be adapted to produce new types of rubber-modified thermoplastics where rubber particles are replaced by rubber-rich domains that do not exhibit definite boundaries. Keywords: