Electron Spin Relaxation in Graphene Nanoribbon Quantum Dots

Abstract: Graphene is promising as a host material for electron spin qubits because of its predicted potential for long coherence times. In armchair graphene nanoribbons (aGNRs) a small bandgap is opened, allowing for electrically gated quantum dots, and furthermore the valley degeneracy is lifted. The spin lifetime T_1 is limited by spin relaxation, where the Zeeman energy is absorbed by lattice vibrations, mediated by spin-orbit and electron-phonon coupling. We have calculated T_1 by treating all couplings analytically and find that T_1 can be in the range of seconds for several reasons: (i) low phonon density of states away from Van Hove singularities; (ii) destructive interference between two relaxation mechanisms; (iii) Van Vleck cancellation at low magnetic fields; (iv) vanishing coupling to out-of-plane modes in lowest order due to the electronic structure of aGNRs. Owing to the vanishing nuclear spin of 12C, T_1 may be a good measure for overall coherence. These results and recent advances in the controlled production of graphene nanoribbons make this system interesting for spintronics applications.