Broken Dynamic Symmetry and Phase Transition Precursor

Abstract: Symmetry breaking is a central concept of Landau phase transition theory, which, however, only considers time-averaged static symmetry of crystal lattice while neglects dynamic symmetry of lattice vibrations thus fails to explain the ubiquitous transformation precursor phenomena. We show that incomplete phonon softening prior to phase transformation leads to dynamic symmetry breaking, whose natural consequences manifest as various precursor "anomalies" that have been difficult to understand from traditional theory. Our experimental observation of heterogeneous phonon domains in high-static-symmetry austenite phase of thermoelastic Ni-Mn-Ga single crystals before martensitic transformation by using three-dimensional synchrotron X-ray phonon diffuse scattering confirms the idea of dynamic symmetry breaking. It provides a natural mechanism and physical understanding of ubiquitous phase transition precursor phenomena in metals, alloys and ceramics.