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Calculation of the orthorhombic E-parameter in EPR for d3 spin systems

Published 3 May 2011 in cond-mat.mtrl-sci | (1105.0616v1)

Abstract: Third order perturbation theory is used to calculate the orthorhombic spin-Hamiltonian zero-field E-term for octahedrally surrounded d3 spin systems (S = 3/2) in strong axial fields in the presence of a weak orthorhombic component.

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