The linear viscoelastic fracture theory applies to soft solids better when they are... viscoelastic

Abstract: Over the last half-century, linear viscoelastic models for crack growth in soft solids have flourished but their predictions have rarely been compared to experiments. In fact, most available models are either very approximate or cast in forms which are not quite suitable for the analysis of actual data. Here, we propose a linear viscoelastic approach which consistently exploits the dynamic mechanical analysis data. We apply this method to four sets of results documenting fracture or adhesion rupture in soft solids with various degrees of viscoelasticity. For elastomers, the results reproduce the well-known inconsistency of the process zone size. In more viscoelastic systems, however, the present approach is able to match the measured velocity dependence of the rupture energy with physically acceptable process zone sizes. Moreover, our predictions agree with the damage zone sizes measured by mechanoluminescence. Building on these results, we discuss various issues arising when evaluating the linear viscoelastic contribution to the rupture/adhesion energy in soft solids: data quality, physical interpretation of the parameters, validity of simpler approximations and limitations of the present approach.