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Pb$_{10-x}$Cu$_x$(PO$_4$)$_6$O: a Mott or charge transfer insulator in need of further doping for (super)conductivity

Published 8 Aug 2023 in cond-mat.supr-con, cond-mat.mtrl-sci, and cond-mat.str-el | (2308.04427v2)

Abstract: We briefly review the status quo of research on the putative superconductor Pb$_9$Cu(PO$_4$)$_6$O also known as LK-99. Further, we provide {\em ab initio} derived tight-binding parameters for a two- and five-band model, and solve these in dynamical-mean-field theory. The ratio interaction-to-bandwidth makes LK-99 a Mott or charge transfer insulator. Electron or hole doping (which is different from substituting Pb by Cu and thus differs from LK-99) is required to make it metallic and potentially superconducting.

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