A Viscoelastic Model for Droplet Breakup in Dense Emulsions

Abstract: When processing dense emulsions, complex flows stretch and deform droplets to the point of breakup, changing the droplet size distribution and the mechanical properties of the final product. For steady homogeneous flows, a droplet's shape and proclivity to breakup can be inferred from a Capillary number, comparing the strain rate with the typical shape relaxation time. More generally, a droplet's shape depends on its whole history of deformation, and this distinction can be salient under conditions relevant to industrial processing. Here, we develop a coupled population balance and droplet shape evolution model (STEPB) with a breaking rate determined by the droplet's shape. In a first application of the STEPB model, we consider droplet breakup during relaxation of step shear, where we predict non-trivial strain-dependent final daughter droplet distributions. We also compare predictions from STEPB against experimental observations in steady flow conditions, illuminating key weaknesses in the model due to neglected terms.