Linear complexions directly modify dislocation motion in face-centered cubic alloys

Abstract: Linear complexions are defect phases that form in the presence of dislocations and thus are promising for the direct control of plasticity. In this study, atomistic simulations are used to model the effect of linear complexions on dislocation-based mechanisms for plasticity, demonstrating unique behaviors that differ from classical dislocation glide mechanisms. Linear complexions impart higher resistance to the initiation and continuation of dislocation motion when compared to solid solution strengthening in all of the face-centered cubic alloys investigated here, with the exact strengthening level determined by the linear complexion type. Stacking fault linear complexions impart the most pronounced strengthening effect, as the dislocation core is delocalized, and initiation of plastic flow requires a dislocation nucleation event. The nanoparticle and platelet array linear complexions impart strengthening by acting as pinning sites for the dislocations, where the dislocations unpin one at a time through bowing mechanisms. For the nanoparticle arrays, this event occurs even though the obstacles do not cross the slip plane and instead only interact through modification of the dislocation's stress field. The bowing modes observed in the current work appear similar to traditional Orowan bowing around classical precipitates but differ in a number of important ways depending on the complexion type. As a whole, this study demonstrates that linear complexions are a unique tool for microstructure engineering that can allow for the creation of alloys with new plastic deformation mechanisms and extreme strength.