Emergence of interparticle friction in attractive colloidal matter

Abstract: Interparticle friction plays a governing role in the mechanics of particulate materials. However, virtually all experimental studies to date rely on measuring macroscopic responses, and as such it remains largely unknown how frictional effects emerge at the microscopic level. This is particularly challenging in systems subject to thermal fluctuations due to the transient nature of interparticle contacts. Here, we directly relate particle-level frictional arrest to local coordination in an attractive colloidal model system. We reveal that the orientational dynamics of particles slows down exponentially with increasing coordination number due to the emergence of frictional interactions, the strength of which can be tuned simply by varying the attraction strength. Using a simple computer simulation model, we uncover how the interparticle interactions govern the formation of frictional contacts between particles. Our results establish quantitative relations between friction, coordination and interparticle interactions. This is a key step towards using interparticle friction to tune the mechanical properties of particulate materials.