Schroedinger representation of quantum mechanics, Berry connection, and superconductivity (2205.07665v1)

Abstract: The standard quantum mechanical electronic state calculations for molecules and solids uses the Schroedinger representation where the momentum conjugate to the coordinate $q_r$ is given by $-hbar {partial over {partial q_r}}$. This formalism contains an extra $U(1)$ phase degree-of-freedom. We show that it can be regarded as a Berry phase arising from many-electron interaction, and when it is non-trivial, it gives rise to a current carrying ground state identified as the superconducting ground state. The connection between this superconducting state and the BCS one is presented.