Drop Impact on Two-Tier Monostable Superrepellent Surfaces

Abstract: Superrepellency is a favorable non-wetting situation featured by a dramatically reduced solid/liquid contact region with extremely low adhesion. However, drop impact often brings out a notable extension of the contact region associated with rather enhanced water affinity, such renders irreversible breakdowns of superhydrophobicity. Here, we report an alternative outcome, a repeated Cassie-Wenzel-Cassie (CWC) wetting state transition in the microscale occurs when a drop impacts a two-tier superhydrophobic surface, which exhibits a striking contrast to the conventional perspective. Influences of material parameters on the impact dynamics are quantified. We demonstrate that self-cleaning and dropwise condensation significantly benefit from this outcome - dirt particles or small droplets in deep textures can be taken away through the transition. The results reported in this study allows us to promote the strategy to design functional superrepellency materials.