Velocity-dependent dipole forces on an excited atom

Abstract: We present a time-dependent calculation of the velocity-dependent forces which act on an excited atomic dipole in relative motion with respect to ground state atoms of a different kind. Both, its interaction with a single atom and with a dilute atomic plate are evaluated. In either case, the total force consists of a conservative van der Waals component and a non-conservative Rontgen component. On physical grounds, the former corresponds to the velocity-dependent recoil experienced by the excited atom in the processes of absorption and emission of the photons that it exchanges with the ground state atoms on a periodic basis. The latter corresponds to the time-variation of the Rontgen momentum, which is also mediated by the periodic exchange of quasi-resonant photons. We find that, at leading order, all these interactions are linear in the velocity. In the non-retarded regime the van der Waals force dominates, being antiparallel to the velocity. On the contrary, in the retarded regime the velocity-dependent forces oscillate in space, van der Waals and Rontgen forces are of the same order in the atom-atom interaction, and the Rontgen component dominates in the atom-surface interaction.