Vibrational branching ratios and hyperfine structure of $^{11}$BH and its suitability for laser cooling

Abstract: The simple structure of the BH molecule makes it an excellent candidate for direct laser cooling. We measure the branching ratios for the decay of the ${\rm A}^{1}\Pi (v'=0)$ state to vibrational levels of the ground state, ${\rm X}^{1}\Sigma^{+}$, and find that they are exceedingly favourable for laser cooling. We verify that the branching ratio for the spin-forbidden transition to the intermediate ${\rm a}^{3}\Pi$ state is inconsequentially small. We measure the frequency of the lowest rotational transition of the X state, and the hyperfine structure in the relevant levels of both the X and A states, and determine the nuclear electric quadrupole and magnetic dipole coupling constants. Our results show that, with a relatively simple laser cooling scheme, a Zeeman slower and magneto-optical trap can be used to cool, slow and trap BH molecules.