Investigating the influence of hydrophobicity and electrostatics on the particle-scale dynamics and rheology of dense microgel suspensions

Abstract: Colloidal microgel particles such as poly(N-isopropylacrylamide) (PNIPAM) undergo a reversible volume phase transition at a volume phase transition temperature, VPTT, in aqueous media. Although the particles shrink in size as the temperature is raised beyond the VPTT, Romeo et al. [Adv. Mater. 2010, 22, 3441-3445] had previously shown that dense aqueous PNIPAM suspensions transform from one viscoelastic solid-like phase to another, with an intermediate viscoelastic liquid-like phase near the VPTT, due to a change in the inter-particle interaction from hydrophilic to hydrophobic. Here, we show using a combination of experimental techniques that particle hydrophobicity can be significant even below the VPTT and can result in the emergence of attractive gel-like phases. We achieve this by incorporating polar salts such as sodium chloride and potassium chloride, or non-polar additives such as sucrose, to the aqueous medium. Above the VPTT, we observe that suspension rigidity is the highest in the presence of polar salts because of the combined effects of ionic and hydrophobic attractions. In the presence of non-dissociating sucrose, in contrast, the inter-microgel interaction remains hydrophobic across the VPTT. Such easy tunability of interactions by incorporating commonly available chemicals into the suspension medium opens up new avenues for the synthesis of novel metamaterials.