Quantum Transition Probabilities

Abstract: Transition probabilities are an important and useful tool in quantum mechanics. However, in their present form, they are limited in scope and only apply to pure quantum states. In this article we extend their applicability to mixed states and to transitions between quantum effects. We also present their dependence on a measured operation or instrument. We begin by defining our concepts on a general quantum effect algebra. These concepts are illustrated using Holevo operations and instruments. We then present transition probabilities in the special case of the Hilbert space formulation of quantum mechanics. We show that for pure states and particular types of operations the transition probabilities reduce to their usual form. We give examples in terms of L\"uders operations and instruments.