Double magnetic transition, complex field-induced phases, and large magnetocaloric effect in the frustrated garnet compound Mn$_{3}$Cr$_{2}$Ge$_{3}$O$_{12}$

Abstract: A detailed study of the magnetic and magnetocaloric properties of a garnet compound Mn${3}$Cr${2}$Ge${3}$O${12}$ is carried out using x-ray diffraction, magnetization, heat capacity, and neutron diffraction measurements as well as \textit{ab initio} band-structure calculations. This compound manifests two successive magnetic transitions at $T_{\rm N1} \simeq 4.5$ K and $T_{\rm N2} \simeq 2.7$ K. Neutron powder diffraction experiments reveal that these two transitions correspond to the collinear and non-collinear antiferromagnetic ordering of the nonfrustrated Cr$^{3+}$ and frustrated Mn$^{2+}$ sublattices, respectively. The interactions within each of the Cr and Mn sublattices are antiferromagnetic, while the inter-sublattice interactions are ferromagnetic. The $H-T$ phase diagram is quite complex and displays multiple phases under magnetic field, which can be attributed to the frustrated nature of the spin lattice. Mn${3}$Cr${2}$Ge${3}$O${12}$ shows a large magnetocaloric effect with a maximum value of isothermal entropy change $\Delta S_{\rm m} \simeq -23$ J/kg-K and adiabatic temperature change $\Delta T_{\rm ad} \simeq 9$ K for a field change of 7 T. Further, a large value of the relative cooling power ($RCP \simeq 360$ J/kg) demonstrates the promise of using this compound in magnetic refrigeration.