Nano-patterned back-reflector with engineered near-field/far-field light scattering for enhanced light trapping in silicon-based multi-junction solar cells (2305.16462v1)

Abstract: Multi-junction solar cells provide a path to overcome the efficiency limits of standard silicon solar cells by harvesting more efficiently a broader range of the solar spectrum. However, Si-based multi-junction architectures are hindered by incomplete harvesting in the near-infrared (near-IR) spectral range, as Si sub-cells have weak absorption close to the band gap. Here, we introduce an integrated near-field/far-field light trapping scheme to enhance the efficiency of silicon-based multi-junction solar cells in the near-IR range. To achieve this, we design a nanopatterned diffractive silver back-reflector featuring a scattering matrix that optimizes trapping of multiply-scattered light into a range of diffraction angles. We minimize reflection to the 0th-order and parasitic plasmonic absorption in the silver by engineering destructive interference in the patterned back contact. Numerical and experimental assessment of the optimal design on the performance of single-junction Si TOPCon solar cells highlights an improved external quantum efficiency (EQE) over a planar back-reflector (+1.52 mA/cm2). Nanopatterned metagrating back-reflectors are fabricated on GaInP/GaInAsP//Si two-terminal triple-junction solar cells via Substrate Conformal Imprint Lithography (SCIL) and characterized optically and electronically, demonstrating a power conversion efficiency improvement of +0.9%abs over the planar reference. Overall, our work demonstrates the potential of nanophotonic light trapping for enhancing the efficiency of silicon-based multi-junction solar cells, paving the way for more efficient and sustainable solar energy technologies.