On-demand Plasmon Nanoparticle-Embedded Laser-Induced Periodic Surface Structures (LIPSSs) on Silicon for Optical Nanosensing (2205.05294v1)

Abstract: Ultrashort laser pulses allows to deliver electromagnetic energy to matter causing its localized heating that can be used for both material removal via ablation/evaporation and drive interface chemical reactions. Here, we showed that both mentioned processes can be simultaneously combined within straightforward laser nanotexturing of Si wafer in functionalizing solution to produce a practically relevant metal-semiconductor surface nano-morphology. Such unique hybrid morphology represent deep-subwavelength Si LIPSSs with a extremely short period down to 70 nm with their high-aspect-ratio nanotrenches loaded with controllable amount of plasmonic nanoparticles formed $via$ laser-induced decomposition of the precursor noble-metal salts. Moreover, heat localization driving reduction process was utilized to produce surface morphology locally decorated with dissimilar plasmon-active nanoparticles. Light-absorbing deep-subwavelength Si LIPSSs loaded with controllable amount of noble-metal nanoparticles represent an attractive architecture for plasmon-related applications such as optical nanosensing where efficient coupling of the propagating optical waves to highly localized electromagnetic hot spots is a mandatory requirement. To support this statement we demonstrated applicability of such hybrid morphology for fluorescence-based detection of nanomolar concentrations of mercury cations in solution.