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Nonrelativistic energy of tritium-containing hydrogen molecule isotopologues

Published 26 Nov 2021 in physics.chem-ph | (2111.13512v1)

Abstract: The nonrelativistic energy of low lying rovibrational levels of HT, DT, and \T\ is determined to an absolute accuracy of $10{-7}-10{-8}$ cm${-1}$ using the variational method with the four-body nonadiabatic James-Coolidge functions. The new results increase the accuracy of the nonrelativistic component of the energy levels by several orders of magnitude. As a consequence, the total transition energies are improved by at least an order of magnitude.

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