Chiral sensing with achiral isotropic metasurfaces

Abstract: Metasurfaces, the two-dimensional analogues of metamaterials, are ideal platforms for sensing molecular chirality at the nanoscale, e.g. of inclusions of natural optically active molecules, as they offer large accessible areas (they are essentially surfaces) and can accommodate the necessary strong resonances for coupling the probing radiation with the chiral inclusions. Here, we examine theoretically achiral isotropic metasurfaces, and we treat them as polarizable surfaces that support resonant electric and magnetic currents, which are coupled via the chiral inclusions. We derive analytically, and verify numerically, expressions that provide insight to the enhancement mechanism of the magneto-electric coupling and explain why circular dichroism signals (difference in absorption between left- and right- circularly polarized waves) can arise from both the real and the imaginary part of the chirality parameter $\kappa$. Our analysis demonstrates distinct chiroptical signals where the contributions from both the real and imaginary part of $\kappa$ can be independently observed and, based on such measurements, we propose a scheme for the unambiguous determination of an unknown chirality.