High-resolution gas phase spectroscopy of molecules desorbed from an ice surface: a proof-of-principle study

Abstract: High-resolution gas phase spectroscopy techniques in the microwave, millimeter-wave and terahertz spectral ranges can be used to study complex organic molecules desorbed from interstellar ice analogues surface with a high sensitivity. High-resolution gas phase spectroscopy gives unambiguous information about the molecular composition, the molecular structure, and transition frequencies needed for their detection by radio telescopes in various interstellar and circumstellar environments. The results will be useful not only for interpreting astronomical spectra and understanding astrophysical processes, but also for more general studies of gas-surface chemistry. This paper presents a new experimental approach based on a combination of a chirped-pulse Fourier transform microwave spectrometer detection and a low temperature surface desorption experiment. The experimental set-up is benchmarked on the desorption of ammonia ice detected by high-resolution gas phase microwave spectroscopy.