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Detection of a Cooper-Pair Density Wave in Bi$_{2}$Sr$_{2}$CaCu$_{2}$O$_{8+x}$ (1511.08124v3)

Published 25 Nov 2015 in cond-mat.supr-con and cond-mat.str-el

Abstract: The quantum condensate of Cooper-pairs forming a superconductor was originally conceived to be translationally invariant. In theory, however, pairs can exist with finite momentum $Q$ and thereby generate states with spatially modulating Cooper-pair density. While never observed directly in any superconductor, such a state has been created in ultra-cold ${6}$Li gas. It is now widely hypothesized that the cuprate pseudogap phase contains such a 'pair density wave' (PDW) state. Here we use nanometer resolution scanned Josephson tunneling microscopy (SJTM) to image Cooper-pair tunneling from a $d$-wave superconducting STM tip to the condensate of Bi${2}$Sr${2}$CaCu${2}$O${8+x}$. Condensate visualization capabilities are demonstrated directly using the Cooper-pair density variations surrounding Zn impurity atoms and at the Bi${2}$Sr${2}$CaCu${2}$O${8+x}$ crystal-supermodulation. Then, by using Fourier analysis of SJTM images, we discover the direct signature of a Cooper-pair density modulation at wavevectors $Q_{p} \approx (0.25,0)2\pi / a_{0}$;$(0,0.25)2\pi / a_{0}$ in Bi${2}$Sr${2}$CaCu${2}$O${8+x}$. The amplitude of these modulations is ~5% of the homogenous condensate density and their form factor exhibits primarily $s$/$s'$-symmetry. This phenomenology is expected within Ginzburg-Landau theory when a charge density wave with $d$-symmetry form factor and wave vector $Q_{c}=Q_{p}$ coexists with a homogeneous $d$-symmetry superconductor ; it is also encompassed by several contemporary microscopic theories for the pseudogap phase.

Citations (226)

Summary

  • The paper employs scanned Josephson tunneling microscopy to detect ~5% spatial modulations forming a Cooper-pair density wave in Bi₂Sr₂CaCu₂O₈₊ₓ.
  • The study demonstrates the coexistence of a PDW state with the homogeneous d-wave superconducting state using nanometer-scale resolution.
  • Implications of these findings include refining high-Tc superconductivity models and guiding tailored material design for advanced applications.

Detection of a Cooper-Pair Density Wave in Bi₂Sr₂CaCu₂O₈₊ₓ

The paper presented here explores the elusive aspect of superconductivity known as the Cooper-pair density wave (PDW), an anticipated phenomenon within the cuprate pseudogap phase. Using state-of-the-art scanned Josephson tunneling microscopy (SJTM), the authors provide compelling evidence for spatial modulations in the superconducting condensate within Bi₂Sr₂CaCu₂O₈₊ₓ, a high-temperature superconducting material.

The theoretical framework suggests that the quantum condensate of Cooper pairs typically exhibits translational invariance. However, under certain conditions, it is posited that Cooper pairs can form finite momentum states characterized by spatial modulations, thus forming a PDW state. Although such states were previously observed in ultra-cold atomic gases, direct evidence in superconductors had been elusive until now. The researchers focused on Bi₂Sr₂CaCu₂O₈₊ₓ due to its relevance in cuprate superconductors and the speculated existence of a PDW within its pseudogap phase.

Employing SJTM, a technique capable of visualizing the spatial distribution of superfluid densities with nanometer precision, the researchers identified Cooper-pair density variations indicative of a PDW state. Notably, the SJTM technique was adeptly utilized to detect modulations at specific wavevectors 𝒬 ≈ 0.2(2π/𝑎), crucial for discerning the PDW state. The observed modulations were found to be approximately 5% of the homogeneous condensate density, with an s/s’ symmetry form factor.

The paper outlines the experimental challenges inherent in detecting these phenomena, given the significant heterogeneity in electronic tunneling characteristics at the surface of Bi₂Sr₂CaCu₂O₈₊ₓ. Despite these challenges, the authors successfully demonstrated that Zn impurity atoms within the material suppress the Cooper-pair condensate locally, substantiating the SJTM's capability to map the spatial distribution of superconductivity.

A critical finding of this work is the coexistence of this PDW state with the homogeneous d-wave superconducting state. Moreover, the PDW exhibits an s/s’ form factor as opposed to the d-symmetry form factor typically observed in charge density waves (CDWs) within the material, underscoring the novelty of the results in the context of established theoretical predictions.

The implications of detecting a PDW state are manifold. Practically, this understanding could inform the design and deployment of materials with tailored superconducting properties, potentially revolutionizing applications such as quantum computing and magnetically levitated transportation technologies. Theoretically, the findings necessitate a reevaluation of existing models for the pseudogap phase, offering a new lens through which the interplay between superconductivity and electronic order can be understood.

Future research directions prompted by this work include the exploration of PDW states across a broader range of cuprates and other materials exhibiting similar competing orders. Moreover, refining the SJTM approach to achieve even finer resolution or employing complementary techniques could further elucidate the nature and dynamics of PDW states.

In conclusion, the authors provide robust evidence for the existence of a Cooper-pair density wave in Bi₂Sr₂CaCu₂O₈₊ₓ, marking a significant advance in the experimental interrogation of superconducting states within cuprate materials. This work not only confirms longstanding theoretical predictions but also enriches the ongoing discourse on the complex nature of high-temperature superconductivity.

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