On the Origin of the Second-Order Nonlinearity in Strained Si-SiN Structures

Abstract: The development of efficient low-loss electro-optic and nonlinear components based on silicon or its related compounds, such as nitrides and oxides, is expected to dramatically enhance silicon photonics by eliminating the need for non-CMOS-compatible materials. While bulk Si is centrosymmetric and thus displays no second-order (\c{hi}(2)) effects, a body of experimental evidence accumulated in the last decade demonstrates that when a strain gradient is present, a significant \c{hi}(2) and Pockels coefficient can be observed. In this work we connect a strain-gradient-induced \c{hi}(2) with another strain-gradient-induced phenomenon, the flexoelectric effect. We show that even in the presence of an extremely strong strain gradient, the degree by which a nonpolar material like Si can be altered cannot possibly explain the order of magnitude of observed chi^2 phenomena. At the same time, in a polar material like SiN, each bond has a large nonlinear polarizability, so when the inversion symmetry is broken by a strain gradient, a small (few degrees) re-orientation of bonds can engender chi^2 of the magnitude observed experimentally. It is our view therefore that the origin of the nonlinear and electro-optic effects in strained Si structures lies in not in the Si itself, but in the material providing the strain: the silicon nitride cladding.