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Existence of a 3.4 μm absorption band on asteroid (84) Klio

Ascertain whether asteroid (84) Klio exhibits a genuine 3.4 μm absorption band in its JWST/NIRSpec reflectance spectrum and, if present, determine the band center and depth to assess whether the feature is associated with complex organics and/or carbonates on its surface.

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Background

The authors investigated potential absorptions near 3.4 μm—typically linked to complex organics and/or carbonates—by dividing Klio’s reflectance spectrum by a polynomial continuum and fitting a Gaussian. They found that the inferred band parameters vary substantially with the chosen continuum boundaries, reflecting the difficulty of defining a reliable continuum given the dominant 3 μm hydration feature.

Because the derived peak position and depth depend strongly on the continuum choice, the authors could not confirm the reality of a 3.4 μm absorption. Establishing whether this feature exists, and characterizing it if so, would directly inform the presence of carbon-bearing species on Klio.

References

Since the parameters depend on the continuum, and given the difficulty to clearly define the continuum because of the 3 μm band, we cannot assert with certainty that the 3.4 μm band is real.

Compositional characterisation of asteroid (84) Klio with JWST (2510.19717 - Pivert-Jolivet et al., 22 Oct 2025) in Subsection “Analysis of the 3.4 μm and 3.9 μm region” (Section 4.2)