Chiral superfluorescence from perovskite superlattices

Abstract: Superfluorescence (SF), a many-body quantum optics phenomenon, emerges from the collective interactions among self-organized and cooperatively coupled emitters, producing intense burst of ultrashort coherent radiation1-4. While SF has been observed in several solid-state materials5-9, the spontaneous generation of circularly polarized (CP) chiral SF has not been realized. Here, we report room-temperature chiral CP-SF originating from edge states in large-area (>100 um * 100 um), transferable vertically aligned chiral quasi-2D perovskite superlattices. Theoretical quantum optics calculations reveal that chirality-induced photon transport drives the transition from initially incoherent, weakly polarized spontaneous emission to highly polarized CP-SF, amplifying the circular polarization degree up to around 14%. Notably, the polarization helicity is found to flip between forward and backward propagation directions, a characteristic signature of a macroscopic CP dipole transition. Moreover, both the intensity and polarization degree of CP-SF can be tuned under weak magnetic fields, enabling precise control over solid-state quantum light emission at room temperature. Our findings emphasize the crucial role of chirality in establishing large-scale quantum coherence within chiral superlattices, thereby unveiling promising avenues for chirality-controlled quantum spin-optical applications 10,11.