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Fluorescent Biomolecules Detectable in Near-Surface Ice on Europa

Published 10 Mar 2025 in astro-ph.EP | (2503.06971v3)

Abstract: Europa, Jupiter's second Galilean moon, is believed to host a subsurface ocean in contact with a rocky mantle, where hydrothermal activity may drive the synthesis of organic molecules. Of these molecules, abiotic synthesis of aromatic amino acids is unlikely, and their detection on Europa could be considered a biosignature. Fluorescence from aromatic amino acids, with characteristic emissions in the 200-400 nanometer wavelength range, can be induced by a laser and may be detectable where ocean material has been relatively recently emplaced on Europa's surface, as indicated by geologically young terrain and surface features. However, surface bombardment by charged particles from the Jovian magnetosphere and solar ultraviolet (UV) radiation degrades organic molecules, limiting their longevity. We model radiolysis and photolysis of aromatic amino acids embedded in ice, showing dependencies on hemispheric and latitudinal patterns of charged particle bombardment and ice phase. We demonstrate that biosignatures contained within freshly deposited ice in high-latitude regions on the surface of Europa are detectable using laser-induced UV fluorescence, even from an orbiting spacecraft.

Summary

Detection of Fluorescent Biomolecules on Europa

The paper "Fluorescent Biomolecules Detectable in Near-Surface Ice on Europa" explores the potential for detecting biosignatures on Europa, one of Jupiter's moons, focusing on the presence and preservation of fluorescent aromatic amino acids in its icy surface. The authors present a detailed investigation into the potential biosignatures that may be indicative of past or present life, despite Europa's harsh environmental conditions.

Key Findings

Europa is hypothesized to contain a subsurface ocean beneath its icy crust, potentially in contact with a rocky mantle. This makes it a prominent candidate for extraterrestrial biology, especially considering possible hydrothermal activity that may facilitate the synthesis of organic compounds. The paper emphasizes the distinctive capability of aromatic amino acids like phenylalanine, tyrosine, and tryptophan, which fluoresce in the UV spectrum when excited by a laser beam. This fluorescence is crucial for their detection, as it can serve as a biosignature due to the rarity of abiotic pathways for their synthesis.

The paper presents models of the radiolysis and photolysis of these aromatic molecules in Europa's ice. These models account for various bombardment patterns by charged particles from Jupiter’s magnetosphere, highlighting how these factors influence the degradation rates of amino acids within the ice. Particular attention is paid to radiolytic degradation, with the authors using experimental data to simulate the bombardment by electrons and ions and assessing their impact.

Numerical Highlights

The authors demonstrate that these aromatic amino acids may endure in high-latitude regions of Europa’s surface, where less radiation leads to slower degradation rates. Estimates indicate they can survive for hundreds to thousands of years under conditions favorable for their detection via laser-induced fluorescence, suggesting promising targets for future missions.

The models predict detectable fluorescence signals even from orbit, reliant on strategic analysis using sophisticated laser systems. Two detection strategies are discussed: one by an instrument at the surface and one from a spacecraft flyby, with both scenarios showing potential for biosignature recognition, depending on surface age and radiation dose rates.

Implications and Speculations

The implications of detecting fluorescent amino acids on Europa could profoundly impact our understanding of life's distribution beyond Earth. The paper outlines how future missions might exploit these findings, focusing on high-latitude regions or plume ejecta, as these conditions likely optimize molecule preservation and detection probability.

The validation of biosignature presence through this method holds significant promise in evaluating Europa's habitability and guiding astrobiological exploration protocols. The paper calls for more refined constraints on the radiolytic constants of organic compounds in extraterrestrial ice to support these efforts further. Additionally, improving the understanding of Europa's ice phase transitions may maximize the efficacy of fluorescence detection techniques.

In conclusion, this research enhances the feasibility of using UV fluorescence to identify extraterrestrial biosignatures, suggesting how Europa exploration missions could be designed to capitalize on findings regarding radiolytic and photolytic degradation in icy environments. Future missions could use these modeling insights to develop targeted spectroscopy strategies, ultimately enhancing our insights into Europa's subsurface ocean and potential biological activity.

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