A single spin in hexagonal boron nitride for vectorial quantum magnetometry

Abstract: Quantum sensing based on solid-state spin defects provides a uniquely versatile platform for imaging physical properties at the nanoscale under diverse environmental conditions. Operation of most sensors used to-date is based on projective measurement along a single axis combined with computational extrapolation. Here, we show that the individually addressable carbon-related spin defect in hexagonal boron nitride is a multi-axis spin system for vectorial nanoscale magnetometry. We demonstrate how its low symmetry and strongly spin-selective direct and reverse intersystem crossing dynamics provide sub-$\mu$T/$\sqrt{\text{Hz}}$ magnetic-field sensitivity for both on and off-axis bias magnetic field exceeding 50 mT. Alongside these features, the room-temperature operation and the nanometer-scale proximity enabled by the van der Waals host material further consolidate this system as an exciting quantum sensing platform.