Tunable Surface Plasmon-Polaritons Interaction in All-Metal Pyramidal Metasurfaces: Unveiling Principles and Significance for Biosensing Applications

Abstract: The strong coupling of plasmonic resonance modes in conductive pyramidal nanoparticles leads to an increase in the density of free charges on the surface. By ensuring plasmonic coupling in the pyramidal nanoparticle lattice, the achieved field intensity is potentiated. At the same time, a strong coupling between resonant modes is guaranteed, which results in the formation of new hybrid modes. In this manuscript, we demonstrated a tunable double anticrossing interaction that results from the interaction between two Localized Surface Plasmon Resonance (LSPR) modes and a Surface Plasmon Polariton (SPP) wave. The tuning is done as a function of the variation of the angle of incidence of the input electric field. From the double anticrossing, an increase in field intensity in a blue-shifted LSPR mode located in the red wavelength region is observed. This demonstrates that at certain angles of incidence, the intensity field obtained is strongly favored, which would be beneficial for applications such as Surface Enhancement Raman Spectroscopy (SERS). Nanoparticle-based lattices have been widely used for biosensor applications. However, one of the major limitations of this type of device is the low tolerance to high concentrations of biomolecules, which significantly affects their performance. According to the studies carried out for this manuscript, it was demonstrated that the implemented geometry allows for the observation of an LSPR mode, which is responsible for the control and synchronization of other perceived resonances. This mode remains almost invariant when subjected to structural variations or changes in the angle of incidence of the electric field. These characteristics eliminate the limitation mentioned above, allowing for sensitivities 10^3 times higher than those achieved in conventional systems based on LSPR used to detect P. brasiliensis antigen.