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Grand-canonical Thermodynamic Formalism via IFS: volume, temperature, gas pressure and grand-canonical topological pressure (2305.01590v3)

Published 2 May 2023 in math.DS, cond-mat.stat-mech, math-ph, math.MP, and math.PR

Abstract: We consider here a dynamic model for a gas in which a variable number of particles $N \in \mathbb{N}0 := \mathbb{N} \cup {0}$ can be located at a site. This point of view leads us to the grand-canonical framework and the need for a chemical potential. The dynamics is played by the shift acting on the set of sequences $\Omega := \mathcal{A}\mathbb{N}$, where the alphabet is $\mathcal{A} := {1,2,...,r}$. Introducing new variables like the number of particles $N$ and the chemical potential $\mu$, we adapt the concept of grand-canonical partition sum of thermodynamics of gases to a symbolic dynamical setting considering a Lipschitz family of potentials $% (A_N){N \in \mathbb{N}0}$, $A_N:\Omega \to \mathbb{R}$. Our main results will be obtained from adapting well-known properties of the Thermodynamic Formalism for IFS with weights to our setting. In this direction, we introduce the grand-canonical-Ruelle operator: $\mathcal{L}{\beta, \mu}(f)=g$, when, $\beta>0,\mu<0,$ and \medskip $\,\,\,\,\,\,\,\,\,\,\,\,\,\,g(x)= \mathcal{L}{\beta, \mu}(f) (x) =\sum{N \in \mathbb{N}0} e{\beta \, \mu\, N }\, \sum{j \in \mathcal{A}} e{- \,\beta\, A_N(jx)} f(jx). $ \medskip We show the existence of the main eigenvalue, an associated eigenfunction, and an eigenprobability for $\mathcal{L}_{\beta, \mu}*$. We can show the analytic dependence of the eigenvalue on the grand-canonical potential. Considering the concept of entropy for holonomic probabilities on $\Omega\times \mathcal{A}{\mathbb{N}_0}$, we relate these items with the variational problem of maximizing grand-canonical pressure. In another direction, in the appendix, we briefly digress on a possible interpretation of the concept of topological pressure as related to the gas pressure of gas thermodynamics.

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