Noncollinear phase of the antiferromagnetic sawtooth chain (2402.05759v2)

Abstract: The antiferromagnetic sawtooth chain is a prototypical example of a frustrated spin system with vertex-sharing triangles, giving rise to complex quantum states. Depending on the interaction parameters, this system has three phases, of which the gapless non-collinear phase (for strongly coupled basal spins and loosely attached apical spins) has received little theoretical attention so far. In this work, we comprehensively investigate the properties of the non-collinear phase using large-scale tensor network computations which exploit the full SU(2) symmetry of the underlying Heisenberg model. We study the ground state both for finite systems using the density-matrix renormalization group (DMRG) as well as for infinite chains via the variational uniform matrix-product state (VUMPS) formalism. Finite temperatures and correlation functions are tackled via imaginary- or real time evolutions, which we implement using the time-dependent variational principle (TDVP). We find that the non-collinear phase is characterized by a low-momentum peak and a diffuse tail for the apex-apex correlations. Deep into the phase, the pattern sharpens into a peak indicating a 90-degree spiral. The apical spins are soft and highly susceptible to external perturbations; they give rise to a large number of gapless magnetic states that are polarized by weak fields and cause a long low-temperature tail in the specific heat. The dynamic spin-structure factor exhibits additive contributions from a two-spinon continuum (excitations of the basal chain) and a gapless peak at $k=\pi/2$ (excitations of the apical spins). Small temperatures excite the gapless states and smear the spectral weight of the $k=\pi/2$ peak out into a homogeneous flat-band structure. Our results are relevant, e.g., for the material atacamite Cu$_2$Cl(OH)$_3$ in high magnetic fields.