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Astrobiological Potential of Venus Atmosphere Chemical Anomalies and Other Unexplained Cloud Properties (2401.04708v1)

Published 9 Jan 2024 in astro-ph.EP

Abstract: Long-standing unexplained Venus atmosphere observations and chemical anomalies point to unknown chemistry but also leave room for the possibility of life. The unexplained observations include several gases out of thermodynamic equilibrium (e.g. tens of ppm O2, the possible presence of PH3 and NH3, SO2 and H2O vertical abundance profiles), an unknown composition of large, lower cloud particles, and the "unknown absorber(s)". Here we first review relevant properties of the Venus atmosphere and then describe the atmospheric chemical anomalies and how they motivate future astrobiology missions to Venus.

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Summary

  • The paper reveals persistent chemical disequilibrium in Venus' clouds through unusual detections of phosphine and ammonia.
  • It documents unidentified UV absorbers and unexpected Mode 3 particle properties that challenge existing atmospheric models.
  • It advocates for targeted in-situ missions to directly sample cloud chemistry and assess Venus's astrobiological potential.

Analyzing the Astrobiological Potential of Venus: Chemical Anomalies and Cloud Properties

The exploration of Venus, particularly its dense cloud layer, presents intriguing possibilities regarding astrobiology and unexplained chemical phenomena. The comprehensive paper conducted by Petkowski et al. explores the longstanding chemical anomalies observed in the Venusian atmosphere, which hint at the possibility of unknown chemistry or even the presence of life. This analysis provides a detailed review of Venus's atmospheric properties, the chemical anomalies observed, and the motivation these offer for future missions aimed at astrobiological exploration of Venus.

The authors focus on several unexplained atmospheric observations, including the presence of gases such as phosphine (PH₃) and ammonia (NH₃), the mysterious vertical abundance profiles of sulfur dioxide (SO₂) and water (H₂O), and a myriad of molecules detected out of thermodynamic equilibrium in Venusian clouds. Additionally, the analysis explores the unknown composition of the larger cloud particles, termed as "Mode 3 particles," and the "unknown absorbers" responsible for capturing a significant fraction of solar energy at ultraviolet wavelengths. These phenomena have not been adequately explained by existing chemical or planetary evolution models.

Key Findings

  1. Chemical Disequilibrium: The detection of gases like PH₃ and NH₃ in the Venusian atmosphere is especially noteworthy, given that these species are not readily produced under known atmospheric chemistry. The persistent disequilibrium suggests active processes, potentially biological.
  2. Unknown Absorbers: The unidentified UV absorber in the Venusian cloud tops remains a mystery despite extensive investigation. The spectral characteristics of this absorber do not match those of any known substances, leading to various hypotheses, including biological origins.
  3. Mode 3 Particles: The larger, non-spherical cloud particles suggest unknown chemistry or even biological materials. The refractive index measurements indicate that these particles might not be composed solely of concentrated sulfuric acid as previously thought.
  4. Unexplained Gas Profiles: The vertical profiles of gases like SO₂ and H₂O show depletion at cloud levels above 70 km, which current photochemical models cannot account for, hinting at unknown atmospheric processes.

Astrobiological Implications

The prospect of an aerial biosphere within Venus's clouds is supported by the potential presence of phosphine and ammonia, which are traditionally associated with biological processes. The paper stresses the importance of initiating focused in-situ missions to validate these findings and explore the chemical and potentially biological dynamics within Venusian clouds.

Future Directions

The paper advocates for renewed in-situ explorations of Venus with modern scientific instrumentation. Such missions should aim to resolve decades-old atmospheric mysteries, directly sample cloud particles, assess their chemical compositions, and evaluate the possibility of biological activity. A crucial next step involves confirming chemical anomalies like phosphine presence, evaluating the unknown absorbers, and determining the composition and acidity of cloud particles.

In summary, Petkowski et al. provide a compelling case for investigating Venusian clouds' astrobiological potential, citing chemical anomalies as provocations for advancing our understanding of Venus's atmospheric chemistry and habitability. Future missions will be pivotal in either confirming or refuting the suggestions of life or unknown chemical processes, thereby advancing planetary science and astrobiology.

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