Superconductor Pb$_{10-x}$Cu$_x$(PO$_4$)$_6$O showing levitation at room temperature and atmospheric pressure and mechanism (2307.12037v3)

Abstract: A material called LK-99, a modified-lead apatite crystal structure with the composition Pb${10-x}$Cu$_x$(PO$_4$)$_6$O ($0.9<x<1.1$), has been synthesized using the solid-state method. The material exhibits the Ohmic metal characteristic of Pb(6s1) above its superconducting critical temperature, $T_c$, and the levitation phenomenon as Meissner effect of a superconductor at room temperature and atmospheric pressure below $T_c$. A LK-99 sample shows $T_c$ above 126.85$^\circ$C (400 K). We analyze that the possibility of room-temperature superconductivity in this material is attributed to two factors: the first being the volume contraction resulting from an insulator-metal transition achieved by substituting Pb with Cu, and the second being on-site repulsive Coulomb interaction enhanced by the structural deformation in the one-dimensional(D) chain (Cu$^{2+}$-O${1/2}$-Cu$^{2+}$ along the c-axis) structure owing to superconducting condensation at $T_c$. The mechanism of the room-temperature $T_c$ is discussed by 1-D BR-BCS theory.

Overview of Room-Temperature Superconductivity in LK-99

The recent synthesis and analysis of LK-99, a Cu-doped lead apatite superconductor, represents a significant step towards achieving room-temperature superconductivity at atmospheric pressure. This composite material, with the formula Pb<sub\>10-x</sub>Cu_x(PO<sub\>4</sub>)<sub\>6</sub>O, was synthesized using solid-state methods and demonstrates superconducting properties with a critical temperature (T_c) notably above room temperature.

Synthesis and Crystal Structure Analysis

The researchers synthesized LK-99 through a multi-step process involving high-precision control over the incorporation of Cu into the lead apatite structure. X-ray diffraction analysis revealed a modified lead apatite (MLA) structure with distinct shifts in lattice constants, suggesting a volume contraction due to the insulator-metal transition (IMT). The Cu substitution modifies the hexagonal symmetry slightly, and there is evidence of structural distortion from the Cu-O-Cu arrangement along the c-axis.

Evidence of Superconductivity

Room-temperature superconductivity in LK-99 is evidenced by its magnetic response and electrical resistivity. The Meissner effect was demonstrated through temperature-dependent diamagnetic susceptibility measurements. Significant levitation was observed under ambient conditions, albeit with imperfections, indicative of incomplete phase purity or optimized structural features in the sample. Furthermore, a transition from a resistive state to a zero-resistivity state occurs beneath T_c, showcased by an impressive T_c exceeding 400 K.

Mechanism and Theoretical Insights

The paper proposes that room-temperature superconductivity in LK-99 results from a combination of factors grounded in the BR-BCS (Brinkman-Rice and Bardeen-Cooper-Schrieffer) theory. The volume contraction upon transition to a metallic state, driven by Cu doping, is central to enhancing the density of states (DOS) due to increased on-site Coulomb interactions. The LK-99 superconductor is characterized by a one-dimensional conducting chain, highlighting the structural role of Cu<sup\>2+</sup> in a distorted Pb<sub\>10-x</sub>Cu_x(PO<sub\>4</sub>)<sub\>6</sub>O lattice. This model predicts that enhanced electron-phonon coupling leads to a bi-polaronic state, which is vital for the superconducting phase, with T_c values exceeding room temperature through increased DOS divergence.

Implications and Future Prospects

The synthesis of LK-99 opens avenues for the practical application of superconductivity in energy-efficient power transmission technologies, magnetic levitation systems, and potentially pivotal roles in advanced electronics operating at or above room temperature. The findings pave the path for further exploration of similar apatite structures and the role of doping in inducing desirable superconductive properties. Future research is expected to refine synthesis methods to improve phase purity, enhance the reproducibility of results, and explore the theoretical frameworks underpinning the substantial T_c observed in this paper.

In conclusion, the work on LK-99 exemplifies a crucial development in material science, with room-temperature superconductivity offering a promising direction for subsequent progress in both theoretical and applied superconducting technologies. The specific mechanisms described in the paper, such as the distinct roles of Cu doping and lattice distortion, could serve as a model for tailoring other materials towards achieving similar superconductive properties.