The First Room-Temperature Ambient-Pressure Superconductor (2307.12008v1)

Abstract: For the first time in the world, we succeeded in synthesizing the room-temperature superconductor ($T_c \ge 400$ K, 127$^\circ$C) working at ambient pressure with a modified lead-apatite (LK-99) structure. The superconductivity of LK-99 is proved with the Critical temperature ($T_c$), Zero-resistivity, Critical current ($I_c$), Critical magnetic field ($H_c$), and the Meissner effect. The superconductivity of LK-99 originates from minute structural distortion by a slight volume shrinkage (0.48 %), not by external factors such as temperature and pressure. The shrinkage is caused by Cu$^{2+}$ substitution of Pb$^{2+}$(2) ions in the insulating network of Pb(2)-phosphate and it generates the stress. It concurrently transfers to Pb(1) of the cylindrical column resulting in distortion of the cylindrical column interface, which creates superconducting quantum wells (SQWs) in the interface. The heat capacity results indicated that the new model is suitable for explaining the superconductivity of LK-99. The unique structure of LK-99 that allows the minute distorted structure to be maintained in the interfaces is the most important factor that LK-99 maintains and exhibits superconductivity at room temperatures and ambient pressure.

• The paper demonstrates the first room-temperature ambient-pressure superconductor, LK-99, exhibiting superconductivity above 400K with currents up to 7 mA and magnetic fields up to 3000 Oe.
• It utilizes a modified lead-apatite structure where copper substitution induces a 0.48% volume shrinkage, forming superconducting quantum wells evidenced by EPR signals.
• The findings pave the way for advancements in energy transmission and quantum computing, motivating further research into stress-induced superconductivity mechanisms.

The First Room-Temperature Ambient-Pressure Superconductor

The paper under consideration reports the synthesis and experimental validation of a room-temperature ambient-pressure superconductor, designated as LK-99. This material is based on a modified lead-apatite (Pb$_{10-x}$ Cu$_x$(PO$_4$)$_6$O) structure, where copper substitutes a fraction of lead atoms, inducing a minute structural distortion that is purportedly responsible for its superconducting properties.

Key Experimental Findings

LK-99 exhibits superconductivity at temperatures exceeding 400 K, a significant advancement in achieving superconductivity under practically viable ambient conditions. The superconductivity has been confirmed through multiple indicators including critical temperature (T$_c$), zero-resistivity, critical current (I$_c$), and the Meissner effect. The material demonstrates a polycrystalline morphology, and the superconducting phase persists for currents up to 7 mA at 400 K and under magnetic fields up to 3000 Oe.

Structural and Mechanistic Insights

The superconductivity in LK-99 appears to originate from a slight volume shrinkage of 0.48%, leading to structural distortion facilitated by the substitution of Cu$^{2+}$ ions for Pb$^{2+}$ ions within the lattice. This distortion generates what the authors term as superconducting quantum wells (SQWs) at the interface between lead and phosphate arrangements. The creation of a 2-dimensional electron gas (2-DEG) in these interfaces is evidenced by Electron Paramagnetic Resonance (EPR) signals, akin to cyclotron resonance observed in SQWs.

Implications and Future Directions

The synthesis of a room-temperature superconductor functioning at ambient pressure denotes a substantial leap in material science, holding implications for a multitude of applications, from power transmission to quantum computing elements like qubits. The theoretically appealing notion of superconductivity arising from intrinsic structural characteristics rather than external factors such as pressure paves the way for further exploration into stress-induced electronic states and their role in superconductivity.

Furthermore, the findings could invoke renewed interest in the paper of structural and electronic properties of similar quasi-one-dimensional systems. Future work may explore optimizing the reproducibility of LK-99, addressing the stability of the superconducting phase, and elucidating the potential quantum mechanical nature of the SQWs. Further research is also warranted to explore the techno-economic feasibility of LK-99 in practical applications, along with a deeper theoretical understanding that ties the observed phenomena to broader superconductivity theories.

In conclusion, while the successful synthesis of a room-temperature, ambient-pressure superconductor marks a significant milestone, the pathway to technological breakthroughs will depend on the continued experimental and theoretical advancement that illuminates the complexities of LK-99 and materials alike.