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Phosphine Gas in the Cloud Decks of Venus (2009.06593v1)

Published 14 Sep 2020 in astro-ph.EP

Abstract: Measurements of trace-gases in planetary atmospheres help us explore chemical conditions different to those on Earth. Our nearest neighbor, Venus, has cloud decks that are temperate but hyper-acidic. We report the apparent presence of phosphine (PH3) gas in Venusian atmosphere, where any phosphorus should be in oxidized forms. Single-line millimeter-waveband spectral detections (quality up to ~15 sigma) from the JCMT and ALMA telescopes have no other plausible identification. Atmospheric PH3 at ~20 parts-per-billion abundance is inferred. The presence of phosphine is unexplained after exhaustive study of steady-state chemistry and photochemical pathways, with no currently-known abiotic production routes in Venusian atmosphere, clouds, surface and subsurface, or from lightning, volcanic or meteoritic delivery. Phosphine could originate from unknown photochemistry or geochemistry, or, by analogy with biological production of phosphine on Earth, from the presence of life. Other PH3 spectral features should be sought, while in-situ cloud and surface sampling could examine sources of this gas.

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Summary

  • The paper reports the detection of ~23 ppb phosphine in Venus' clouds using JCMT and ALMA observations.
  • The paper employs millimeter-wave spectral analysis and polynomial fitting to mitigate noise and extract the phosphine signal.
  • The paper rules out known abiotic processes, thereby opening new discussions on potential biological or unknown geochemical sources.

Overview of the Phosphine Detection in Venus’ Clouds

The reported research investigates the detection of phosphine ((PH)) gas in the atmosphere of Venus, leveraging observations conducted using the JCMT and ALMA telescopes. The research identifies phosphine in Venus' cloud decks at an estimated abundance of ~23 parts-per-billion. This detection is of particular interest because there are no known abiotic processes on Venus that could produce phosphine in such quantities. The research was motivated by the proposal that phosphine could be an indicator of biological processes; on Earth, life forms produce phosphine in negligible amounts within oxidized environments.

Methodological Approaches

The paper employs single-line millimeter-waveband spectral detections, emphasizing the use of the PH 1-03 transition observed at 1.123 mm wavelength. Observations were conducted using the JCMT over several mornings, and follow-up observations were completed using ALMA. To extract meaningful data despite significant spectral ‘ripple’ and noise, the paper implements multiple data reduction techniques involving polynomial fitting over the spectral ripple. The research utilizes both whole-planet spectra and latitudinally segmented spectra, with data for validation extracted through the phase calibration executed on the bandpass calibrator Callisto.

Results and Implications

The observations indicate consistent phosphine absorption features, aligned with Venus’ velocity, detected across two independent telescopic systems. The paper's methodology rules out the possibility of line-contamination from other molecular species, with an extensive assessment excluding plausible candidates like SO. Additionally, the observed spectral feature is verified against both narrowband and wideband spectral data to ensure robustness.

Potential Sources and Speculation

The research addresses several potential non-biological phosphine production mechanisms such as steady-state atmospheric and surface chemistry, meteorological delivery, and photochemical reactions; all these are found to be insufficient by several orders of magnitude in explaining the detected abundance of phosphine. Photochemical and geochemical pathways would require unknown chemical processes, or, by analogy with life on Earth, a biological source.

Critical Evaluation and Future Directions

While this paper compellingly argues that known chemical processes could not account for the phosphine levels observed, it stops short of asserting the presence of life. The environmental conditions on Venus are notably hostile to life as understood in terrestrial terms, presenting significant challenges to theorizing life there. To further explore this anomaly, future research could focus on deeper atmospheric assessment through additional spectral lines of phosphine, direct sampling missions to Venus' atmosphere, and advancing photochemical and geochemical models tailored to Venusian conditions.

Beyond Venus, this type of research could serve as a template for assessing biosignatures in exoplanetary studies, providing a base methodology for remote detection and verification of potential biosignature gases in other planetary atmospheres.

In conclusion, the paper highlights the potential for further inquiry into the Venusian atmosphere, encouraging both model-based investigations and direct exploratory missions to elucidate the source of the detected phosphine. Whether this points to an unknown chemical process, an exotic geochemical cycle, or potential life forms remains an open and intriguing question for astrobiologists and planetary scientists.

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