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Saturation of the Infrared Absorption by Carbon Dioxide in the Atmosphere (2004.00708v2)

Published 27 Mar 2020 in physics.ao-ph

Abstract: Based on new radiative transfer numerical evaluations, we reconsider an argument presented by Schack in 1972 that says that saturation of the absorption of infrared radiation by carbon dioxide in the atmosphere sets in as soon as the relative concentration of carbon dioxide exceeds a lower limit of approximately 300 ppm. We provide a concise brief and explicit representation of the greenhouse effect of the earth's atmosphere. We find an equilibrium climate sensitivity (temperature increase $\Delta T$ due to doubling of atmospheric $CO_2$ concentration) of $\Delta T \simeq 0.5 0C$. We elaborate on the consistency of these results on $\Delta T$ with results observationally obtained by satellite-based measurements of short-time radiation-flux versus surface-temperature changes.

Citations (4)

Summary

  • The paper confirms that CO₂ infrared absorption saturates around 300 ppm, indicating that further CO₂ increases produce diminishing warming effects.
  • The study employs radiative transfer models, spectroscopic data, and satellite observations to robustly validate its theoretical predictions.
  • The analysis reveals an equilibrium climate sensitivity of ~0.5°C for CO₂ doubling, with water vapor significantly reducing the radiative forcing.

An Expert Overview of "Saturation of the Infrared Absorption by Carbon Dioxide in the Atmosphere"

The paper "Saturation of the Infrared Absorption by Carbon Dioxide in the Atmosphere" by Dieter Schildknecht revisits a subject initially broached by Schack in 1972 regarding the greenhouse gas effect of CO₂. The primary focus of this paper is the concept that the infrared absorption of CO₂ becomes saturated when concentrations exceed approximately 300 ppm, which aligns with its modern atmospheric levels.

Key Findings

  • Infrared Absorption Saturation: The paper confirms that the saturation of infrared radiation by atmospheric CO₂ occurs, leading to a situation where additional increases in CO₂ concentration have a diminished effect on the absorption of radiation. Schildknecht finds that saturation is effectively attained at 0.03% (300 ppm), in agreement with atmospheric observations.
  • Equilibrium Climate Sensitivity: Schildknecht's analysis presents an equilibrium climate sensitivity (ECS) of about 0.5°C for a doubling of CO₂ concentrations. This finding goes against some contemporary predictions that typically locate ECS between 1.5°C and 4.5°C.
  • Water Vapor Role: The presence of water vapor significantly affects the absorption dynamics of CO₂. The inclusion of water vapor reduces the impact of doubling CO₂ from approximately 6 W/m² to about 2.6 W/m², resulting in a temperature increase of around 0.46°C. This reinforces the notion that water vapor is a critical factor in modulating the greenhouse effect.

Methodology

The author utilizes detailed radiative transfer calculations backed by spectroscopic data and employs absorption models to estimate CO₂ interaction with infrared radiation. Radiative transfer models take into account both dry and moist atmospheric conditions, providing a more comprehensive view of climate dynamics. Moreover, this paper leverages observational satellite data to cross-verify theoretical predictions.

Implications

  • Theoretical Insights: The findings hint at a saturation effect in CO₂-induced greenhouse warming, a subject warranting further exploration due to its implications for climate predictions and policy-making.
  • Practical Implications: If true, the saturation effect could signify that further anthropogenic CO₂ emissions might have a relatively limited impact on temperature increments compared to existing predictions, impacting climate change mitigation strategies.

Speculation on Future Developments

Looking ahead, understanding the saturation effects of CO₂ in conjunction with other greenhouse gases, like water vapor, becomes increasingly crucial. Incorporating these dynamics into complex climate models could lead to more accurate predictions. Further investigations might include coupling atmospheric models with oceanic and land processes to evaluate the comprehensive impacts of greenhouse gases.

Conclusion

Schildknecht’s work contributes to the nuanced comprehension of CO₂’s role in climate dynamics by re-evaluating the extent of its infrared absorption. While it raises questions about current projections of the greenhouse effect, the conclusions drawn must be approached with rigor, considering variabilities and complexities inherent in atmospheric science. Continued multi-disciplinary research is essential for refining these models and shaping informed climate policies.

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