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Fluctuation-Dissipation: Response Theory in Statistical Physics (0803.0719v1)

Published 5 Mar 2008 in cond-mat.stat-mech and nlin.CD

Abstract: General aspects of the Fluctuation-Dissipation Relation (FDR), and Response Theory are considered. After analyzing the conceptual and historical relevance of fluctuations in statistical mechanics, we illustrate the relation between the relaxation of spontaneous fluctuations, and the response to an external perturbation. These studies date back to Einstein's work on Brownian Motion, were continued by Nyquist and Onsager and culminated in Kubo's linear response theory. The FDR has been originally developed in the framework of statistical mechanics of Hamiltonian systems, nevertheless a generalized FDR holds under rather general hypotheses, regardless of the Hamiltonian, or equilibrium nature of the system. In the last decade, this subject was revived by the works on Fluctuation Relations (FR) concerning far from equilibrium systems. The connection of these works with large deviation theory is analyzed. Some examples, beyond the standard applications of statistical mechanics, where fluctuations play a major role are discussed: fluids, granular media, nano-systems and biological systems.

Citations (625)

Summary

  • The paper provides a comprehensive review of the fluctuation-dissipation relation (FDR) and response theory, tracing its historical development and extending applications to various non-equilibrium systems.
  • It details the theoretical framework including Kubo's formalism for linear response and extends it to stochastic dynamics, discussing applications for non-Hamiltonian systems and chaotic attractors.
  • The review highlights extensive practical applications of FDR in diverse fields such as fluid dynamics, climate systems, granular materials, nano-systems, and biological systems, even in non-equilibrium contexts.

Insightful Overview of "Fluctuation-Dissipation: Response Theory in Statistical Physics"

The paper "Fluctuation-Dissipation: Response Theory in Statistical Physics" by Umberto Marini Bettolo Marconi et al. aims to provide a comprehensive review of the fluctuation-dissipation relation (FDR) and response theory, extending its applications to various systems beyond traditional statistical mechanics. Set against a historical backdrop, it traverses the development from Einstein's pioneering work on Brownian motion to modern applications in non-equilibrium systems.

Historical Context and Evolution of FDR

The discussion begins with historical abstractions, noting the criticism of atomistic theories which gave way to Einstein and Smoluchowski's work on Brownian motion. This work critically affirmed the existence of atoms through empirical studies. The paper revisits the fluctuation phenomena incorporated in Einstein's explorations and extends into Onsager's regression hypothesis, establishing the groundwork for FDR by relating the macroscopic relaxation processes to microscopic fluctuations.

Theoretical Framework

Central to the paper is the investigation of FDR, initially conceived within Hamiltonian systems and later generalized for broader applications. The authors explicate the classical linear response theory, including Kubo's contributions, which form the backbone of understanding systems' responses to perturbations.

  • Kubo's Formalism: It provides expressions connecting transport coefficients to correlations of currents, utilizing Green-Kubo relations, which the authors detail for diffusion, shear flow, and other transport processes.
  • Stochastic Processes: The response formalism is extended to stochastic dynamics, considering Langevin and Fokker-Planck equations. These formulations permit the computation of response functions using fluctuation-dissipation equations even for non-Hamiltonian systems.

Generalized FDR and Chaos

The paper tackles van Kampen's objection to linear response considerations, presenting arguments that support the robustness of FDR even in chaotic systems due to ensemble averaging and mixing properties. This part sheds light on the nature of chaotic attractors and their implications for statistical mechanics.

Practical Implications and Applications

One significant contribution of the review is its extensive focus on non-standard applications, such as turbulence in fluids, climate systems, granular materials, nano-systems, and biological systems. These cases showcase how FDR plays a pivotal role even in non-equilibrium and highly non-linear contexts. For instance, it covers:

  • Fluid Dynamics: Addresses how equilibrium statistical mechanics principles apply to inviscid fluids and turbulent systems, and how FDR assists in closure problems and turbulence modeling.
  • Climate Systems: The adaptation of FDR for climate modeling suggests a systematic approach to studying atmospheric responses to perturbations, underscoring their time-scale dependencies.
  • Granular Materials: The discussion extends to statistical properties and kinetic models of granular flows, which are paramount due to their non-equilibrium steady states.
  • Biological Systems: Potential applications in understanding biological fluctuations hint at a broader interpretative scope for FDR in complex living systems.

Future Perspectives and Conclusions

The paper concludes by addressing future directions and potential developments. It anticipates further engagement with systems displaying anomalous diffusion, as well as the potential cross-pollination between theoretical advancements and computational simulations. The authors suggest a blurred line between theory and practical simulation use, which could foster enhanced predictive models across disciplines.

Overall, the review presents a lucid synthesis of FDR's developmental history, its extended theoretical formulations, and the richness of its applications in contemporary science, providing an indispensable resource for researchers in statistical mechanics and its interdisciplinary extensions.

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