Strong NUV Refractory Absorption and Dissociated Water in the Hubble Transmission Spectrum of the Ultra Hot Jupiter KELT-20 b

Abstract: Ultra hot Jupiters (UHJs) present a promising pathway for drawing a link between a planet's composition and formation history. They retain both refractory and volatiles species in gas phase in their atmospheres, which allows us to place unique constraints on their building blocks. Here, we present the 0.2 - 1.7 $\mu$m transmission spectrum of KELT-20 b/MASCARA-2 b taken with the Hubble Space Telescope (HST). Unlike other UHJs around early-type stars, KELT-20 b's orbit is well aligned with its host star's spin axis and we test whether its distinct dynamical configuration is reflected in its composition. We observe a tremendous rise (>10 scale heights) in the planet's transit depth at the near-UV wavelengths, akin to that observed for WASP-178 b and WASP-121 b, and a muted water absorption feature in the near-IR. Our retrievals indicate that the large NUV depth is driven by Fe II and/or SiO and that the water is mostly thermally dissociated. Assuming equilibrium chemistry, we obtain constraints on Z/H and O/H that indicate accretion of volatile-rich solids and/or gas. Both our low resolution spectrum and the refractory elemental ratios from Gandhi et al. 2023 suggest that nightside condensation and rainout are limited to only the most refractory species in the planet's atmosphere. Within the precision limits of the HST spectra, no strong evidence for limb asymmetry is detected. We contextualize this lack of asymmetry by comparing to predictions from general circulation models with and without the effects of kinematic magnetohydrodynamics. Lastly, we find no major differences in the HST transmission spectra of KELT-20 b, WASP-178, and WASP-121 b despite their different dynamical configurations.