Quantum metric-based optical selection rules (2507.09260v1)

Abstract: The optical selection rules dictate symmetry-allowed/forbidden transitions, playing a decisive role in engineering exciton quantum states and designing optoelectronic devices. While both the real (quantum metric) and imaginary (Berry curvature) parts of quantum geometry contribute to optical transitions, the conventional theory of optical selection rules in solids incorporates only Berry curvature. Here, we propose quantum metric-based optical selection rules. We unveil a universal quantum metric-oscillator strength correspondence for linear polarization of light and establish valley-contrasted optical selection rules that lock orthogonal linear polarizations to distinct valleys. Tight-binding and first-principles calculations confirm our theory in two models (altermagnet and Kane-Mele) and monolayer $d$-wave altermagnet $\mathrm{V_2SeSO}$. This work provides a quantum metric paradigm for valley-based spintronic and optoelectronic applications.