Lithium doping's effects on the microstructural,dielectric,energy storage,optical and electrical properties of BaTi0.89Sn0.11O3 ceramics (2503.16006v1)

Abstract: This research study the sol/gel synthesis of lithium-doped barium stannate titanate BaTi0.89Sn0.11O3 (BTS11) and investigates how varying composition with lithium affect its structural, morphological, ferroelectric, optical, and electrical properties. The phase of the sol/gel prepared samples with different compositions BaLixTi0.89Sn0.11O3 (BLxTS11), where x = 0%, 2%, 4%, 6%, 8, and 10%, was examined using X-ray diffraction (XRD), which showed the development of a pure perovskite structure. Furthermore, structural characterization was performed with Raman spectroscopy to identify changes in structure and chemical environment resulting from Li incorporation. The doping caused changes in the morphology and grain size of BLxTS11 pellets, as examined through SEM micrographs. These micrographs showed clear alterations in grain size that were inversely related to the lattice strain of BLxTS11. The samples were subsequently examined for their ferroelectric properties. All samples exhibited their maximum dielectric constant at approximately 45-50 {\deg}C. Furthermore, relationships between the chemical, structural, and morphological characteristics of the BLxTS11 ceramics and their energy storage capabilities were identified. Based on the P-E hysteresis behavior, the BL6TS11 ceramic (x=6%) ferroelectric exhibited superior energy-storage capabilities, featuring a recoverable energy-storage density of 225 mJ/cm3 and an energy-storage efficiency of 60%. An examination of the material's optical and electrical properties revealed that Li doping led to a reduction in the band gap values and a considerable increase in resistivity.