Metallic ruthenium ilmenites: first-principles study of MgRuO$_3$ and CdRuO$_3$ (2306.11542v1)

Abstract: Ilmenites $AB$O$3$ provide a platform for electron correlation and magnetism on alternatively stacked honeycomb layers of edge-sharing $A$O$_6$ or $B$O$_6$ octahedra. When $A$ and $B$ are $3d$ transition metals, strong electron correlation makes the systems Mott insulators showing various magnetic properties, while when $B$ is Ir with $5d$ electrons, competition between electron correlation and spin-orbit coupling realizes a spin-orbital coupled Mott insulator as a potential candidate for quantum spin liquids. Here we theoretically investigate intermediate $4d$ ilmenites, $A$RuO$_3$ with $A$=Mg and Cd, which were recently synthesized and shown to be metallic, unlike the $3d$ and $5d$ cases. By using first-principles calculations, we optimize the lattice structures and obtain the electronic band structures. We show that MgRuO$_3$ exhibits strong dimerization on RuO$_6$ honeycomb layers, leading to the formation of bonding and anti-bonding bands for one of three $t{2g}$ orbitals; the lattice symmetry is lowered from $R\bar{3}$ to $P\bar{1}$, and the Fermi surfaces are composed of the other two $t_{2g}$ orbitals. In contrast, we find that CdRuO$3$ has a lattice structure close to $R\bar{3}$, and all three $t{2g}$ orbitals contribute almost equally to the Fermi surfaces. Comparison of our results with other Ru honeycomb materials such as Li$_2$RuO$_3$ indicates that the metallic ruthenium ilmenites stand on a subtle balance among electron correlation, spin-orbit coupling, and electron-phonon coupling.