Papers
Topics
Authors
Recent
Gemini 2.5 Flash
Gemini 2.5 Flash
117 tokens/sec
GPT-4o
8 tokens/sec
Gemini 2.5 Pro Pro
47 tokens/sec
o3 Pro
5 tokens/sec
GPT-4.1 Pro
38 tokens/sec
DeepSeek R1 via Azure Pro
28 tokens/sec
2000 character limit reached

Non-Equilibrium Dynamics in Two-Color, Few-Photon Dissociative Excitation and Ionization of D$_2$ (2106.09014v1)

Published 16 Jun 2021 in physics.atom-ph, physics.chem-ph, physics.optics, and quant-ph

Abstract: D$_2$ molecules, excited by linearly cross-polarized femtosecond extreme ultraviolet (XUV) and near-infrared (NIR) light pulses, reveal highly structured D$+$ ion fragment momenta and angular distributions that originate from two different 4-step dissociative ionization pathways after four photon absorption (1 XUV + 3 NIR). We show that, even for very low dissociation kinetic energy release $\le$~240~meV, specific electronic excitation pathways can be identified and isolated in the final ion momentum distributions. With the aid of {\it ab initio} electronic structure and time-dependent Schr\"odinger equation calculations, angular momentum, energy, and parity conservation are used to identify the excited neutral molecular states and molecular orientations relative to the polarization vectors in these different photoexcitation and dissociation sequences of the neutral D$_2$ molecule and its D$_2+$ cation. In one sequential photodissociation pathway, molecules aligned along either of the two light polarization vectors are excluded, while another pathway selects molecules aligned parallel to the light propagation direction. The evolution of the nuclear wave packet on the intermediate \Bstate electronic state of the neutral D$_2$ molecule is also probed in real time.

Summary

We haven't generated a summary for this paper yet.