Understanding the mechanism of oxygen evolution reaction (OER) with the consideration of spin (2004.05326v1)

Abstract: Oxygen evolution reaction (OER) with intractable high overpotential is the rate-limiting step for rechargeable metal-air battery, water electrolysis systems, and solar fuels devices. There exists a spin state transition from spin singlet OH-/H2O reactant to spin triplet O2 product, which has not received enough attention yet. In this perspective, we attempt to retrospect electron behaviours during the whole OER process, with the consideration of spin attribute. Regardless of the adopted mechanisms by different electrocatalysts, for example, adsorbate evolution mechanism (AEM) or lattice oxygen mechanism (LOM), the underlying rationale is that active sites have to extract three in four electrons with the same spin direction before the formation of O=O. This spin-sensitive nature of OER superimposes additional high requirements on the electrocatalysts, especially on the spin structure, to compliment the fast electron transfer in the interface with spin selection and smoothly delivery afterwards. When optimizing the geometric and electronic structures catering for the spin-sensitive OER, awareness of the couplings between spin, charge, orbital and lattice is necessary. Some spin-correlated physical properties, such as (1) crystal field, (2) coordination, (3) oxidation, (4) bonding, (5) eg electron number, (6) conductivity and (7) magnetism, are also discussed briefly. It is hoped that our perspective could shed lights on the underlying physics of the slow kinetics of OER, providing a rational guidance for more effective energy conversion electrocatalysts designs.